AV 8596 then JA 5133 at Bogotá
Cali → Bogota → Medellín
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
11:05JA 5133 to Medellín leaves the gate
18 h 35 apart on the timetable, overnight
JA 5133 leaves 18 h 35 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.