AV 8596 then LA 4116 at Bogotá
Cali → Bogota → Cartagena
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
07:20LA 4116 to Cartagena leaves the gate
14 h 50 apart on the timetable, overnight
LA 4116 leaves 14 h 50 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.