AV 8596 then T9 881 at Bogotá
Cali → Bogota → Valencia (Venezuela)
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
10:00T9 881 to Valencia (Venezuela) leaves the gate
17 h 30 apart on the timetable, overnight
T9 881 leaves 17 h 30 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.