AV 9245 then AV 2906 at Bogotá
Medellín → Bogota → Popayan
Timetable, Bogota time
07:10AV 9245 from Medellín at the gate
05:35AV 2906 to Popayan leaves the gate
22 h 25 apart on the timetable, overnight
AV 2906 leaves 22 h 25 after AV 9245 arrives on the timetable: more than half a day, so not a connection we count.