AV 9544 then AV 5055 at Bogotá
Cali → Bogota → Buenos Aires Ezeiza
Timetable, Bogota time
05:50AV 9544 from Cali at the gate
20:30AV 5055 to Buenos Aires Ezeiza leaves the gate
14 h 40 apart on the timetable
AV 5055 leaves 14 h 40 after AV 9544 arrives on the timetable: more than half a day, so not a connection we count.