AV 9544 then LA 4216 at Bogotá
Cali → Bogota → Cucuta
Timetable, Bogota time
05:50AV 9544 from Cali at the gate
04:30LA 4216 to Cucuta leaves the gate
22 h 40 apart on the timetable, overnight
LA 4216 leaves 22 h 40 after AV 9544 arrives on the timetable: more than half a day, so not a connection we count.