AV 9544 then P5 7458 at Bogotá
Cali → Bogota → Valencia (Venezuela)
Timetable, Bogota time
05:50AV 9544 from Cali at the gate
05:00P5 7458 to Valencia (Venezuela) leaves the gate
23 h 10 apart on the timetable, overnight
P5 7458 leaves 23 h 10 after AV 9544 arrives on the timetable: more than half a day, so not a connection we count.