AV 9566 then VB 8236 at Bogotá
Cali → Bogota → Valledupar
Timetable, Bogota time
19:40AV 9566 from Cali at the gate
18:50VB 8236 to Valledupar leaves the gate
23 h 10 apart on the timetable, overnight
VB 8236 leaves 23 h 10 after AV 9566 arrives on the timetable: more than half a day, so not a connection we count.