AV 9887 then LA 4404 at Bogotá
Quito → Bogota → Caracas
Timetable, Bogota time
05:35AV 9887 from Quito at the gate
04:10LA 4404 to Caracas leaves the gate
22 h 35 apart on the timetable, overnight
LA 4404 leaves 22 h 35 after AV 9887 arrives on the timetable: more than half a day, so not a connection we count.