LA 4005 then LA 4404 at Bogotá
Medellín → Bogota → Caracas
Timetable, Bogota time
06:40LA 4005 from Medellín at the gate
04:10LA 4404 to Caracas leaves the gate
21 h 30 apart on the timetable, overnight
LA 4404 leaves 21 h 30 after LA 4005 arrives on the timetable: more than half a day, so not a connection we count.