LA 4062 then JA 5110 at Bogotá
Cali → Bogota → Medellín
Timetable, Bogota time
07:55LA 4062 from Cali at the gate
05:00JA 5110 to Medellín leaves the gate
21 h 05 apart on the timetable, overnight
JA 5110 leaves 21 h 05 after LA 4062 arrives on the timetable: more than half a day, so not a connection we count.