LA 4064 then 9R 8604 at Bogotá
Cali → Bogota → Medellin
Timetable, Bogota time
08:55LA 4064 from Cali at the gate
07:359R 8604 to Medellin leaves the gate
22 h 40 apart on the timetable, overnight
9R 8604 leaves 22 h 40 after LA 4064 arrives on the timetable: more than half a day, so not a connection we count.