LA 4064 then JA 5110 at Bogotá
Cali → Bogota → Medellín
Timetable, Bogota time
08:50LA 4064 from Cali at the gate
06:40JA 5110 to Medellín leaves the gate
21 h 50 apart on the timetable, overnight
JA 5110 leaves 21 h 50 after LA 4064 arrives on the timetable: more than half a day, so not a connection we count.