LA 4598 then JA 5642 at Bogotá
Cali → Bogota → Cucuta
Timetable, Bogota time
06:25LA 4598 from Cali at the gate
19:10JA 5642 to Cucuta leaves the gate
12 h 45 apart on the timetable
JA 5642 leaves 12 h 45 after LA 4598 arrives on the timetable: more than half a day, so not a connection we count.