VE 9169 then VB 8104 at Bogotá
Popayan → Bogota → Medellín
Timetable, Bogota time
19:05VE 9169 from Popayan at the gate
17:50VB 8104 to Medellín leaves the gate
22 h 45 apart on the timetable, overnight
VB 8104 leaves 22 h 45 after VE 9169 arrives on the timetable: more than half a day, so not a connection we count.