AZ 148 then SN 3245 at Brussels
Milan Linate → Brussels → Athens
Timetable, Brussels time
08:35AZ 148 from Milan Linate at the gate
07:00SN 3245 to Athens leaves the gate
22 h 25 apart on the timetable, overnight
SN 3245 leaves 22 h 25 after AZ 148 arrives on the timetable: more than half a day, so not a connection we count.