IB 601 then VY 7868 at Brussels
Madrid → Brussels → Valencia
Timetable, Brussels time
19:00IB 601 from Madrid at the gate
15:15VY 7868 to Valencia leaves the gate
20 h 15 apart on the timetable, overnight
VY 7868 leaves 20 h 15 after IB 601 arrives on the timetable: more than half a day, so not a connection we count.