SN 2064 then SN 1573 at Brussels
Edinburgh → Brussels → Alicante
Timetable, Brussels time
18:25SN 2064 from Edinburgh at the gate
16:55SN 1573 to Alicante leaves the gate
22 h 30 apart on the timetable, overnight
SN 1573 leaves 22 h 30 after SN 2064 arrives on the timetable: more than half a day, so not a connection we count.