SN 2064 then SN 3669 at Brussels
Edinburgh → Brussels → Toulouse
Timetable, Brussels time
18:25SN 2064 from Edinburgh at the gate
15:45SN 3669 to Toulouse leaves the gate
21 h 20 apart on the timetable, overnight
SN 3669 leaves 21 h 20 after SN 2064 arrives on the timetable: more than half a day, so not a connection we count.