SN 2064 then SN 3727 at Brussels
Edinburgh → Brussels → Madrid
Timetable, Brussels time
14:55SN 2064 from Edinburgh at the gate
14:15SN 3727 to Madrid leaves the gate
23 h 20 apart on the timetable, overnight
SN 3727 leaves 23 h 20 after SN 2064 arrives on the timetable: more than half a day, so not a connection we count.