SN 2588 then VY 7868 at Brussels
Berlin → Brussels → Valencia
Timetable, Brussels time
20:00SN 2588 from Berlin at the gate
15:15VY 7868 to Valencia leaves the gate
19 h 15 apart on the timetable, overnight
VY 7868 leaves 19 h 15 after SN 2588 arrives on the timetable: more than half a day, so not a connection we count.