SN 2644 then SN 3751 at Brussels
Munich → Brussels → Valencia
Timetable, Brussels time
13:10SN 2644 from Munich at the gate
09:45SN 3751 to Valencia leaves the gate
20 h 35 apart on the timetable, overnight
SN 3751 leaves 20 h 35 after SN 2644 arrives on the timetable: more than half a day, so not a connection we count.