SN 2646 then VY 7868 at Brussels
Munich → Brussels → Valencia
Timetable, Brussels time
16:15SN 2646 from Munich at the gate
10:35VY 7868 to Valencia leaves the gate
18 h 20 apart on the timetable, overnight
VY 7868 leaves 18 h 20 after SN 2646 arrives on the timetable: more than half a day, so not a connection we count.