SN 2650 then VY 7868 at Brussels
Munich → Brussels → Valencia
Timetable, Brussels time
19:55SN 2650 from Munich at the gate
10:35VY 7868 to Valencia leaves the gate
14 h 40 apart on the timetable, overnight
VY 7868 leaves 14 h 40 after SN 2650 arrives on the timetable: more than half a day, so not a connection we count.