SN 3132 then IB 602 at Brussels
Catania → Brussels → Madrid
Timetable, Brussels time
20:55SN 3132 from Catania at the gate
19:45IB 602 to Madrid leaves the gate
22 h 50 apart on the timetable, overnight
IB 602 leaves 22 h 50 after SN 3132 arrives on the timetable: more than half a day, so not a connection we count.