SN 3132 then SN 2723 at Brussels
Catania → Brussels → Geneva
Timetable, Brussels time
20:55SN 3132 from Catania at the gate
19:20SN 2723 to Geneva leaves the gate
22 h 25 apart on the timetable, overnight
SN 2723 leaves 22 h 25 after SN 3132 arrives on the timetable: more than half a day, so not a connection we count.