SN 3132 then SN 2815 at Brussels
Catania → Brussels → Prague
Timetable, Brussels time
20:55SN 3132 from Catania at the gate
20:45SN 2815 to Prague leaves the gate
23 h 50 apart on the timetable, overnight
SN 2815 leaves 23 h 50 after SN 3132 arrives on the timetable: more than half a day, so not a connection we count.