SN 3176 then SN 2063 at Brussels
Rome → Brussels → Edinburgh
Timetable, Brussels time
12:15SN 3176 from Rome at the gate
09:45SN 2063 to Edinburgh leaves the gate
21 h 30 apart on the timetable, overnight
SN 2063 leaves 21 h 30 after SN 3176 arrives on the timetable: more than half a day, so not a connection we count.