SN 3714 then SN 2587 at Brussels
Bilbao → Brussels → Berlin
Timetable, Brussels time
18:55SN 3714 from Bilbao at the gate
16:25SN 2587 to Berlin leaves the gate
21 h 30 apart on the timetable, overnight
SN 2587 leaves 21 h 30 after SN 3714 arrives on the timetable: more than half a day, so not a connection we count.