SN 3728 then VY 7868 at Brussels
Madrid → Brussels → Valencia
Timetable, Brussels time
19:55SN 3728 from Madrid at the gate
15:15VY 7868 to Valencia leaves the gate
19 h 20 apart on the timetable, overnight
VY 7868 leaves 19 h 20 after SN 3728 arrives on the timetable: more than half a day, so not a connection we count.