SN 3802 then IB 1302 at Brussels
Faro → Brussels → Madrid
Timetable, Brussels time
20:55SN 3802 from Faro at the gate
19:45IB 1302 to Madrid leaves the gate
22 h 50 apart on the timetable, overnight
IB 1302 leaves 22 h 50 after SN 3802 arrives on the timetable: more than half a day, so not a connection we count.