UA 950 then SN 3733 at Brussels
Washington → Brussels → Málaga
Timetable, Brussels time
07:15UA 950 from Washington at the gate
06:05SN 3733 to Málaga leaves the gate
22 h 50 apart on the timetable, overnight
SN 3733 leaves 22 h 50 after UA 950 arrives on the timetable: more than half a day, so not a connection we count.