UX 1173 then VY 7868 at Brussels
Madrid → Brussels → Valencia
Timetable, Brussels time
17:45UX 1173 from Madrid at the gate
15:15VY 7868 to Valencia leaves the gate
21 h 30 apart on the timetable, overnight
VY 7868 leaves 21 h 30 after UX 1173 arrives on the timetable: more than half a day, so not a connection we count.