IB 5867 then SN 2095 at Brussels
Valencia → Brussels → London Heathrow
Timetable, Brussels time
20:15IB 5867 from Valencia at the gatealso VY 7869
16:55SN 2095 to London Heathrow leaves the gate
20 h 40 apart on the timetable, overnight
SN 2095 leaves 20 h 40 after IB 5867 arrives on the timetable: more than half a day, so not a connection we count.