AA 1335 then AA 5829 at Charlotte
Pittsburgh → Charlotte → Tri-Cities
Timetable, Charlotte time
19:24AA 1335 from Pittsburgh at the gate
17:54AA 5829 to Tri-Cities leaves the gate
22 h 30 apart on the timetable, overnight
AA 5829 leaves 22 h 30 after AA 1335 arrives on the timetable: more than half a day, so not a connection we count.