AA 1485 then AA 5197 at Charlotte
Rochester → Charlotte → Valparaiso
Timetable, Charlotte time
08:10AA 1485 from Rochester at the gate
21:23AA 5197 to Valparaiso leaves the gate
13 h 13 apart on the timetable
AA 5197 leaves 13 h 13 after AA 1485 arrives on the timetable: more than half a day, so not a connection we count.