AA 2224 then AA 5332 at Charlotte
Baltimore → Charlotte → Washington
Timetable, Charlotte time
08:45AA 2224 from Baltimore at the gate
07:31AA 5332 to Washington leaves the gate
22 h 46 apart on the timetable, overnight
AA 5332 leaves 22 h 46 after AA 2224 arrives on the timetable: more than half a day, so not a connection we count.