AA 2224 then AA 5969 at Charlotte
Baltimore → Charlotte → Charlottesville
Timetable, Charlotte time
08:45AA 2224 from Baltimore at the gate
07:15AA 5969 to Charlottesville leaves the gate
22 h 30 apart on the timetable, overnight
AA 5969 leaves 22 h 30 after AA 2224 arrives on the timetable: more than half a day, so not a connection we count.