AA 2814 then AA 5793 at Charlotte
Chicago O'Hare → Charlotte → Charlottesville
Timetable, Charlotte time
11:15AA 2814 from Chicago O'Hare at the gate
10:25AA 5793 to Charlottesville leaves the gate
23 h 10 apart on the timetable, overnight
AA 5793 leaves 23 h 10 after AA 2814 arrives on the timetable: more than half a day, so not a connection we count.