AA 3026 then AA 5543 at Charlotte
Madison → Charlotte → Pittsburgh
Timetable, Charlotte time
15:32AA 3026 from Madison at the gate
08:35AA 5543 to Pittsburgh leaves the gate
17 h 03 apart on the timetable, overnight
AA 5543 leaves 17 h 03 after AA 3026 arrives on the timetable: more than half a day, so not a connection we count.