AA 3241 then AA 5921 at Charlotte
Pittsburgh → Charlotte → Asheville
Timetable, Charlotte time
21:55AA 3241 from Pittsburgh at the gate
21:01AA 5921 to Asheville leaves the gate
23 h 06 apart on the timetable, overnight
AA 5921 leaves 23 h 06 after AA 3241 arrives on the timetable: more than half a day, so not a connection we count.