AA 3333 then AA 3268 at Charlotte
Pittsburgh → Charlotte → Punta Cana
Timetable, Charlotte time
15:13AA 3333 from Pittsburgh at the gate
07:10AA 3268 to Punta Cana leaves the gate
15 h 57 apart on the timetable, overnight
AA 3268 leaves 15 h 57 after AA 3333 arrives on the timetable: more than half a day, so not a connection we count.