AA 3371 then AA 5220 at Charlotte
Little Rock → Charlotte → Washington
Timetable, Charlotte time
09:46AA 3371 from Little Rock at the gate
09:45AA 5220 to Washington leaves the gate
23 h 59 apart on the timetable, overnight
AA 5220 leaves 23 h 59 after AA 3371 arrives on the timetable: more than half a day, so not a connection we count.