AA 3521 then AA 5111 at Charlotte
Valparaiso → Charlotte → Manchester
Timetable, Charlotte time
15:37AA 3521 from Valparaiso at the gate
13:57AA 5111 to Manchester leaves the gate
22 h 20 apart on the timetable, overnight
AA 5111 leaves 22 h 20 after AA 3521 arrives on the timetable: more than half a day, so not a connection we count.