AA 3521 then AA 5968 at Charlotte
Valparaiso → Charlotte → Charlottesville
Timetable, Charlotte time
15:37AA 3521 from Valparaiso at the gate
15:27AA 5968 to Charlottesville leaves the gate
23 h 50 apart on the timetable, overnight
AA 5968 leaves 23 h 50 after AA 3521 arrives on the timetable: more than half a day, so not a connection we count.