AA 439 then AA 2569 at Charlotte
Washington National → Charlotte → San Francisco
Timetable, Charlotte time
13:30AA 439 from Washington National at the gate
12:00AA 2569 to San Francisco leaves the gate
22 h 30 apart on the timetable, overnight
AA 2569 leaves 22 h 30 after AA 439 arrives on the timetable: more than half a day, so not a connection we count.