AA 5064 then AA 5131 at Charlotte
Manchester → Charlotte → New Orleans
Timetable, Charlotte time
08:20AA 5064 from Manchester at the gate
20:35AA 5131 to New Orleans leaves the gate
12 h 15 apart on the timetable
AA 5131 leaves 12 h 15 after AA 5064 arrives on the timetable: more than half a day, so not a connection we count.