AA 5064 then AA 6066 at Charlotte
Manchester → Charlotte → Tallahassee
Timetable, Charlotte time
08:20AA 5064 from Manchester at the gate
20:50AA 6066 to Tallahassee leaves the gate
12 h 30 apart on the timetable
AA 6066 leaves 12 h 30 after AA 5064 arrives on the timetable: more than half a day, so not a connection we count.