AA 5075 then AA 5814 at Charlotte
Roanoke → Charlotte → Huntington
Timetable, Charlotte time
17:29AA 5075 from Roanoke at the gate
17:20AA 5814 to Huntington leaves the gate
23 h 51 apart on the timetable, overnight
AA 5814 leaves 23 h 51 after AA 5075 arrives on the timetable: more than half a day, so not a connection we count.