AA 5180 then AA 5543 at Charlotte
White Plains → Charlotte → Pittsburgh
Timetable, Charlotte time
15:43AA 5180 from White Plains at the gate
08:35AA 5543 to Pittsburgh leaves the gate
16 h 52 apart on the timetable, overnight
AA 5543 leaves 16 h 52 after AA 5180 arrives on the timetable: more than half a day, so not a connection we count.